Web2-(2-Bromoaryl)imidazoles react with cyclohexane-1,3-diones in the presence of a catalytic amount of recyclable Fe3O4@SiO2@MOF-199 and a base to give the corresponding C–C coupled and cyclized products 6,7-dihydroimidazo[1,2-f]phenanthridin-8(5H)-ones in high yields. The magnetic MOF catalyst could be easily recovered and reused four times … Web4. jan 2014 · Their 13 C-NMR spectra of these 5-benzyl-1-(2′,4′-dibromophenyl)-3-(4″-substituted phenyl,4,6,6a-tetrahydro-1H,5H-pyrrolo[3,4-c]pyrazole-4,6-dione derivatives 5 display characteristic signals in the range of δ 171.2–171.8 and 171.0–171.6 which have been assigned to two succinimide carbonyl carbons, signals in the range of δ 143.7 ...
1,3-Diphenyl-1,3-propanedione 120-46-7 東京化成工業株式会社
WebA series of substituted 2-phenyl-4-quinolones have been synthesized in good yields flash vacuum thermolysis (FVT) of 1-aryl-4-cyano-5-phenylpyrrole-2,3-diones and 1-aryl-4 … Web1. mar 2024 · Here we identified novel SIRT1 inhibitors with the scaffold of 5-benzylidene-2-phenyl-1,3-dioxane-4,6-dione. The most potent inhibitor 12n displayed an IC 50 of 460 nM … the diwan hall
Competitive One-Pot Reactions: Simultaneous Synthesis of ...
WebPropanedinitrile, 2-(4,7-dihydroxy-5-phenyl-2H-benzo[d]1,3-dithiol-2-ylideno)- C16H8N2O2S2 CID 629634 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity … Web1. dec 2016 · With the optimized reaction conditions in hand (Table 1, entry 1), we then explored the substrate scope for this base-free O-difluoromethylation of 1,3-diones with PDFA (Scheme 1).A variety of 1,3-cyclohexanediones (2a-2 h) and 1,3-cyclopentanediones (2i-2m) were converted smoothly into the corresponding products in moderate to high … Web24. mar 2008 · Reductive desymmetrization of 2-methyl-2-substituted-cycloalkane-1,3-diones can be effected using either NaBH 4 in DME or lithium tri-tert-butoxyaluminum hydride (LTBA) in THF at −60 °C. The former is a new approach that offers slightly greater diastereoselectivity in the reduction of 2,2-disubstituted-cyclopentane-1,3-diones while … tax treaty luxembourg indonesia